Metasploit contains modules that enable the injection of payload exploits into legitimate files as part of crafting social engineering attacks. Given that Metasploit has this functionality, it is indeed possible to deliver a payload via a tampered PDF file. However, Metasploit is not designed for deep packet inspection or wireless network attacks, as these are the functions of Wireshark and Aircrack-ng, respectively.
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What are Metasploit modules and how do they work?
What is a social engineering attack and how is it related to Metasploit?
What are the roles of Wireshark and Aircrack-ng in penetration testing?